
Petro Dyachenko was a Ukrainian military commander who served as a staff captain in the Russian Army, colonel in the Ukrainian People's Army (1917–1921), major in the Polish Army (1928–1939), officer in the Volhynian Self-Defence Legion, commander of Panzerjagd-Brigade Vilna Ukraina (1945), and Colonel in the Ukrainian National Army (1945) and commander of the 2nd Division UNA.

Leonid Kostyantynovych Kadenyuk was the first, and to this day remains the only, astronaut of independent Ukraine who flew into outer space. He flew on NASA's Space Shuttle Columbia in 1997 as part of the international mission STS-87. Kadenyuk held the rank of Major General in the Ukrainian Air Force.

Volodymyr Panteleimonovych Oskilko was a Ukrainian military activist and administrator. He became famous for the historical Oskilko's Affair.

Symon Vasylyovych Petliura (Ukrainian: Си́мон Васи́льович Петлю́ра; 22 May [O.S. 10 May] 1879 – May 25, 1926) was a Ukrainian politician and journalist. He became the Supreme Commander of the Ukrainian Army and the President of the Ukrainian People's Republic during Ukraine's short-lived sovereignty in 1918–1921, leading Ukraine's struggle for independence following the fall of the Russian Empire in 1917.

Colonel General Serhiy Mikolayovych Popko is a Ukrainian military general and the Commander of the Ukrainian Ground Forces (2016-2019). Previously, Popko was the commanding officer of the Ukrainian Anti-Terrorist Operation. He is a graduate of the Kyiv Higher Combined Arms Command School. In 2017, he was promoted to colonel general.

Alexander Pavlovich Rodzyanko was an officer of the Imperial Russian Army during the World War I and lieutenant-general and a corps commander of the White Army during the Russian Civil War.

Volodymyr Petrovych Salsky was a Ukrainian general, minister of defense, head of the Ukrainian government in exile.

Pavlo Shandruk was a general in the army of the Ukrainian National Republic, a colonel of the Polish Army, and a prominent general of the Ukrainian National Army, a military force that fought against the Soviets under German command at the close of World War II.

Mykola Shapoval (1886–1948) was a military, public and political figure, Major General of the Ukrainian People's Army. He was a brother to Mykyta Shapoval and Artem Shapoval and married to Antonina Hladun.

Andrei Grigoriyevich Shkuro was a Lieutenant General (1919) of the White Army.

Roman-Taras Yosypovych Shukhevych, also known by his pseudonym Taras Chuprynka, was a Ukrainian nationalist, one of the commanders of Nachtigall Battalion, a hauptmann of the German Schutzmannschaft 201 auxiliary police battalion, a military leader of the Ukrainian Insurgent Army (UPA), and one of the organizers of the Halych-Volhyn Massacre.

Volodymyr Oleksandrovych Sinkler or Vladimir Sinclair was a Ukrainian military leader, general of the Russian army, and general of the Ukrainian People's Army.

Pavlo Petrovych Skoropadskyi was a Ukrainian aristocrat, military and state leader, decorated Imperial Russian Army and Ukrainian Army general of Cossack heritage. Skoropadsky became a conservative leader in Ukraine following the Russian Revolution of 1917, a founder of a hetman dynasty and Hetman of Ukraine.

Mykola V. Tsybulenko (1942–1998) was a Ukrainian major general.

Vladimir Alekseevich Varyukhin — Soviet and Ukrainian scientist, Professor, Doctor of Technical Sciences, Honored Scientist of the UkrSSR, Major-General, founder of the theory of multichannel analysis, creator of the scientific school on digital antenna arrays (DAAs).

Ihor Oleksandrovych Voronchenko is a Ukrainian Vice Admiral and a former commander of the Ukrainian Navy.

Mykola Yunakiv was a Ukrainian general, military pedagogue. He was a general in the army of the Russian Empire and the Ukrainian People's Republic.