
Volhynian Voivodeship was a unit of administrative division and local government in the Grand Duchy of Lithuania from 1566 until 1569 and of the Polish Crown within the Polish–Lithuanian Commonwealth from the 1569 Union of Lublin until the Third Partition of Poland in 1795. It was part of the Ruthenian lands in the Lesser Poland Province.
Baranivka is a town and the administrative center of Baranivka Raion in Zhytomyr Oblast, Ukraine. Population: 11,497 (2020 est.) . In 2001 the population was 12,584.

Bilohiria is an urban-type settlement in the Khmelnytskyi Oblast of western Ukraine. It serves as the administrative center of the Bilohiria Raion (district)</ref>, housing the district's local administration buildings. The town's population was 5,592 as of the 2001 Ukrainian Census and 5,212 (2020 est.) Nearby towns include Yampil, Kremenets, and Kornytsya.

Dubno is a city located on the Ikva River in Rivne Oblast (province) of western Ukraine. Serving as the administrative center of Dubno Raion (district), Dubno is incorporated as a city of oblast significance and does not belong to the raion. The city is located on intersection of two major European routes E40 and E85. Population: 37,464 (2020 est.) It is located within the historic region of Volhynia.

Iziaslav or Zaslav is one of the oldest cities in Volhynia. Situated on the Horyn river in western Ukraine, the city dates back to the 11th century. Population: 16,336 (2020 est.)

Kamin-Kashyrskyi is a town in Volyn Oblast, Ukraine. It is the administrative center of Kamin-Kashyrskyi Raion. Population: 12,477 (2020 est.)

Korets is a city in Rivne Oblast in Ukraine. The city is located on the Korchyk river, 66 kilometers to the east of Rivne. It is administrative center of Korets Raion. Population: 6,984 (2020 est.)

Kovel is a city in Volyn Oblast (province), in northwestern Ukraine. Serving as the administrative center of Kovel Raion (district), the town itself is designated as a town of oblast significance and is not part of the raion. Population: 68,240 (2020 est.)

Kremenets is a city of regional significance in the Ternopil Oblast (province) of western Ukraine. It is the administrative center of the Kremenets Raion (district), and lies 18 km north-east of the great Pochayiv Monastery. The city is situated in the historic region of Volhynia. Popularion: 20,827 (2020 est.)

Lutsk is a city on the Styr River in northwestern Ukraine. It is the administrative center of the Volyn Oblast (province) and the administrative center of the surrounding Lutsk Raion (district) within the oblast, though it is not a part of the raion. Lutsk has the status of a city of oblast significance, equivalent to that of a raion. Population: 217,315 (2020 est.)

Novohrad-Volynskyi is a city in the Zhytomyr Oblast (province) of northern Ukraine. Originally known as Zvyahel, the city was renamed in 1795 after annexation of territories of Polish-Lithuanian Commonwealth by the Russian Empire soon after the third Partition of Poland.

Olevsk is a city in Olevsk Raion, Zhytomyr Oblast, Ukraine. It is the administrative center of Olevsk Raion. Population: 10,305 (2020 est.)

Ostroh is a historic city located in Rivne Oblast (province) of western Ukraine, on the Horyn River. Ostroh is the administrative center of the Ostroh Raion (district). Administratively, Ostroh is incorporated as a city of oblast significance and does not belong to the raion. Population: 15,457 (2020 est.)

Ostropol, also known as Staryy Ostropil, is a small town on the Sluch River located in the Khmelnytskyi Oblast about 133 miles (222 km) WSW of Kyiv, Ukraine. It is located at latitude 49°48' N, longitude 27°34' E and is situated at an altitude of 742.5 feet. The town of Lyubar is 11.1 miles (18.5 km) from Ostropol.

Pryvitne is a small village in the Lokachi Raion, Volyn Oblast of western Ukraine. It is located approximately 75 miles northeast of the city of Lviv, Ukraine. In the past it was a town of Świniuchy.

Radyvýliv is a small city in Rivne Oblast (region) of western Ukraine. It is the administrative center of Radyvyliv Raion (district), and is located south-west of the oblast capital, Rivne, near European route E40. The nearest larger cities are Dubno, and Brody; the latter being 10 km (6 mi) away. In Soviet times, from 1939 to 1992, the city was known as Chervonoarmiysk. 10,476 (2020 est.)

Rivne is a historic city in western Ukraine. It is the administrative center of Rivne Oblast (province), as well as the surrounding Rivne Raion (district) within the oblast. Administratively, Rivne is incorporated as a city of oblast significance and does not belong to the raion. Population: 246,003 (2020 est.)

Rožýšče is a town in Volyn Oblast, Ukraine. It serves as an administrative center of Rozhyshche Raion. Population: 12,710 (2020 est.)
Slavuta is a city of oblast subordinance in the Khmelnytskyi Oblast (province) of western Ukraine, located on the Horyn River. (district), the city itself is also designated as a separate raion within the oblast, and is located approximately 80 km from the oblast capital, Khmelnytskyi, at around 50°18′N 26°52′E. Population: 35,230 (2020 est.)
Starokostiantyniv is a city in the Khmelnytskyi Oblast (province) of western Ukraine. Population: 34,455 (2020 est.)

Staryi Chortoryisk is a village (selo) in north-western Ukraine. It is located on the bank of the Styr River in the Manevychi Raion (district) of the Volyn Oblast (province).

Stepan is an urban-type settlement in Sarny Raion (district) of Rivne Oblast (province) in western Ukraine. Its population was 4,073 as of the 2001 Ukrainian Census. Current population: 4,095 (2020 est.)

Turiisk is an urban settlement (town) in Volyn Oblast (province), located in the historic region of the Volhynia. It is an administrative seat of the Turiisk Raion. Population: 5,836 (2020 est.)

Volodymyr-Volynskyi is a small city located in Volyn Oblast, in north-western Ukraine. Serving as the administrative centre of the Volodymyr-Volynskyi Raion, the city itself is also designated as a separate municipality within the oblast as the city of regional significance. The city is the historic centre of the region of Volhynia and the historic capital of the Principality of Volhynia. Population: 38,340 (2020 est.)

Volodymyrets is an urban-type settlement in Rivne Oblast (province) in western Ukraine. The town is also the administrative center of Volodymyrets Raion (district), housing the district's local administration buildings. Its population is 8,699 as of the 2001 Ukrainian Census. Current population: 9,311 (2020 est.)

Vyshnivets is an urban-type settlement in the Zbarazh Raion (district) of the Ternopil Oblast (province) of western Ukraine. Population: 3,236 (2020 est.)

Zbarazh is a city in the Ternopil Oblast (province) of western Ukraine. It is the administrative center of the Zbarazh Raion (district), and is located in the historic region of Galicia. Population: 13,587 (2020 est.)