
Francisco Higinio Andrade Marín was Ecuadorian politician. He was Minister of Finance in 1894. He was President of the Chamber of Deputies in 1911. He was acting President of Ecuador from 6 March to 10 August 1912.

Manuel de Ascázubi y Matheu served as Vice President of Ecuador from 1847 to 1849 and in that capacity he was also interim President from 16 October 1849 to 10 June 1850.

Diego Borja Cornejo is an Ecuadorian economist and politician born in Quito, Ecuador. Between 2005 and 2006 he served as Minister of Economy and Finance. He was elected member of the National Constitutional Assembly on September 30, 2007. He resigned this position to be appointed Coordination Minister for Economic Policy on December 23, 2008

Rafael Carvajal Guzmán (1818–1881) was Vice President of Ecuador from 1864 to 1865 and acting President from 31 August 1865 to 7 September 1865.

Rafael Vicente Correa Delgado, known as Rafael Correa, is an Ecuadorian politician and economist who served as President of Ecuador from 2007 to 2017. The leader of the PAIS Alliance political movement from its foundation until 2017, Correa is a democratic socialist and his administration focused on the implementation of left-wing policies. Internationally, he served as president pro tempore of the UNASUR.

Alberto Dahik Garzozi is an Ecuadorian politician of Lebanese ancestry. He was Vice President of Ecuador from August 10, 1992 to October 11, 1995 during the Sixto Durán Ballén administration.

José Javier Eguiguren Ríofrío was acting President of Ecuador from 6 October 1875 to 9 December 1875.

Juan Antonio María Flores y Jijón de Vivanco as 13th President of Ecuador 17 August 1888 to 30 June 1892. He was a member of the Progressive Party, a Liberal Catholic party.

Carlos Freile Larrea was Ecuadorian politician. He was acting President of Ecuador from 27 August 1932 to 2 September 1932. He was Minister of Finance from 1939 to 1940.

Juan García del Río was a Colombian diplomat, writer and politician.

Gabriel Gregorio Fernando José María García Moreno y Morán de Butrón, Knight with the Collar of the Order of Pope Pius IX, was an Ecuadorian politician who twice served as President of Ecuador and was assassinated during his second term, after being elected to a third. He is noted for his conservatism, Catholic religious perspective and rivalry with liberal strongman Eloy Alfaro. Under his administration, Ecuador became a leader in science and higher education within Latin America. In addition to the advances in education and science, he was noted for economically and agriculturally advancing the country, as well as for his staunch opposition to corruption, even giving his own salary to charity.

Lizardo García Sorroza was President of Ecuador from 1 September 1905 to 15 January 1906.

Juan de Dios Martínez Mera was 23rd President of Ecuador from 1932 to 1933. He was President of the Chamber of Deputies in 1921. He was Minister of Finance from 1929 to 1930, and from 1931 to 1932.

Ricardo Armando Patiño Aroca is an Ecuadorian politician who has served as Minister of Foreign Affairs of Ecuador from 2010 until 2016, under the government of President Rafael Correa. Previously he was Minister of Finance and Minister of the Coast. He is one of the ideologists of The Citizens' Revolution who with Correa wanted to gradually introduce a democratic socialist government in Ecuador. On 4 March 2016, he was name as Defense Minister by President Correa.

Rodrigo Paz Delgado was an Ecuadorian politician and businessman. He was the mayor of Quito from 1988 to 1992. He ran as a presidential candidate in 1995/6. One of his political parties was Democracia Popular (DP).

Leónidas Plaza y Gutiérrez de Caviedes was an Ecuadorian politician who was the President of Ecuador from September 1, 1901 to August 31, 1905 and again from September 1, 1912 to August 31, 1916.

Mauricio Pozo Crespo is an Ecuadorian politician, banker and economist from Quito, Ecuador. Since 2020, he has been Minister of Economy and Finance.

Vicente Lucio Salazar was Acting President of Ecuador between 16 April 1895 and 1 September 1895.

José Serrano Salgado is an Ecuadorian politician. He was President of the National Assembly between 14 May 2017 and 9 March 2018. He was Minister of the Interior from 13 May 2011 to 15 November 2016. He previously held other cabinet posts.

María Elsa Viteri was an Ecuadorian economist and politician. She served as Minister of Finance from 2008 to 2010 and again in 2018. Viteri died on 18 November 2021 after a battle with pancreatic cancer.