
The following is a list of governors of Venezuela Province, one of the Provinces of the Spanish Empire.

The Captaincy General of Venezuela, also known as the Kingdom of Venezuela, was an administrative district of colonial Spain, created on September 8, 1777, through the Royal Decree of Graces of 1777, to provide more autonomy for the provinces of Venezuela, previously under the jurisdiction of the Audiencia of Santo Domingo and then the Viceroyalty of New Granada. It established a unified government in political (governorship), military, fiscal (intendancy), ecclesiastical (archdiocese) and judicial (audiencia) affairs. Its creation was part of the Bourbon Reforms and laid the groundwork for the future nation of Venezuela, in particular by orienting the province of Maracaibo towards the province of Caracas.

Juan Manuel Cajigal y Niño was a Spanish Captain General, born in Cádiz, in 1754.

Vicente Emparán was a Spanish Basque Captain General.

Miguel de la Torre y Pando, conde de Torrepando was a Spanish General, Governor and Captain General, who served in Spain, Venezuela, Colombia and Puerto Rico during the Spanish American wars of independence and afterwards.

Juan Domingo de Monteverde y Rivas, commonly known as Domingo de Monteverde, was a Spanish soldier, governor and Captain General of Venezuela from June 1812 to 8 August 1813. Monteverde was the leader of Spanish forces in the Venezuelan War of Independence from 1812 to 1813. Monteverde led the military campaign that culminated in the fall of the First Republic of Venezuela in 1812. One year later in 1813, Monteverde was defeated by Simón Bolívar during the Admirable Campaign.
Francisco Tomás Morales, was a Spanish military, and the last of that country to hold the post of Captain General of Venezuela, reaching the rank of field marshal during the Venezuelan War of Independence.

Pablo Morillo y Morillo, Count of Cartagena and Marquess of La Puerta, a.k.a. El Pacificador was a Spanish general.